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Lithium bis(trimethylsilyl)amide(1070-89-9)use
2014-07-28
来源:亚科官网
One, the basic information
CAS number: 4039-32-1
Molecular formula: C6H18LiNSi2
Molecular weight: 167.3269
Chinese Name: Six methyl two silazane lithium salt; bis - (three methyl silicon)lithium amide
English Name: Lithium Hexamethyldisilazide
[(CH3) 3Si]2NLi, LiHMDS, Bis (trimethylsilyl) amine lithium salt
Two, use
Non dear nuclear alkali, can be used to form enol enol ester reaction,stereospecific Claisen rearrangement, the aldehyde into silicon reactions of imines, generating glycidyl ester reaction, beta lactam reaction, selective cleavage of alkyl aryl ethers reaction.